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Agri. & Environ.
Vitamin C and chromium 6, a deadly combination
By Boram Lee - foodconsumer.org
Mar 14, 2007 - 4:32:45 PM

Chromium 6 and vitamin C, a deadly combination

PROVIDENCE , R.I. - Vitamin C can kill. That is, when mixed with chromium 6.  

Naturally occurring vitamin C reacts inside human lung cells with chromium 6, or hexavalent chromium, causing massive DNA damage, according to Brown University researchers.

When combined with vitamin C, even low doses of chromium 6 can produce up to 15 times as many chromosomal breaks and up to 10 times more mutations than cells that lack vitamin C altogether.   Such phenomena are forms of genetic damage that lead to cancer.

However, vitamin C is not always harmful.   In fact, when outside cells, vitamin C protects against the cellular damage caused by hexavalent chromium, according to Anatoly Zhitkovich, an associate professor of medical science at Brown who oversaw the experiments.  

Vitamin C has been used as an antidote in industrial accidents when large amounts of chromium were ingested. This was the case in the Hollywood blockbuster, Erin Brockovich that featured the compound hexavalent chromium as its villain .  

Vitamin C is a powerful antioxidant that blocks cellular damage from free radicals.  As it rapidly adds electrons, to free radicals, the vitamin converts them into harmless molecules. This electron transfer produces chromium 3, a form of the compound unable to enter cells.

However, expect the unexpected when chromium and vitamin C come together, inside cells.

 Zhitkovich and his team conducted experiments using human lung cells supplemented with vitamin C.   When vitamin C was present, chromium reduction had a very different effect. Cellular vitamin C sparked considerably more chromosomal breaks and cellular mutations, acting as a potent toxic amplifier.

Increasing the concentration of vitamin C inside cells provoked more mutations and DNA breaks, turning chromium toxic, said Zhitkovich.   It had been unknown until now, with the presence of vitamin C, how exposure to small amounts of hexavalent chromium can cause high rates of cancer.  

Hexavalent chromium is a compound used to make paints, dyes, plastics and inks, and to plate metals.  Hexavalent chromium is found in 40 percent of Superfund sites nationwide and causes lung cancer.

The research, published in Nucleic Acids Research, may have policy implications, according to Zhitkovich,. Chromium 6 caused genetic damage in cells in doses four times lower than current federal standards when combined with vitamin C, Zhitkovich said.  

He also said federal regulators might want to lower exposure standards if additional research backs these findings.







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